There are more than twenty rules that kids must remember when they attempt to syllabicate words. Most times it is very hard to remember all of them so the next best thing is to get lots and lots of practice! Let them listen to words and try to figure out how many syllables there are. Engage them in activities which call for looking closely at words to look for patterns as well. The more they listen to the sounds of words and the more they look at the words that they say the more likely they are to discover the rules of syllabication naturally!
If you are interested in a syllabication literacy center for kindergarten kids click the picture below.